NEW COMPLEXES OF INDIUM (111) CONTAINING MIXED LIGANDS (SEMICARBAZONES and BENZALDAZINES).

Authors

  • Z.F DAWOOD Mosul University

Keywords:

Ligands, semicarbazone, benzaldazine, indium

Abstract

Mixed ligand complexes of indium (111) have been synthesized by the reaction of InCl3.6H2O with semicarbazone (SCH) and benzaldazine (BA) ligands in neutral and basic medium. Complexes of the type [In2 (BA)2 (LH)4]Cl6 and [In2 (BA)2 (L)4]Cl2 (where BA = benzaldazine, LH = semicarbazone ligands (SCH) and L = deprotonated semicarbazone ligands (SC)) have been proposed in neutral and basic medium, respectively. The complexes are characterized physicochemically.

Downloads

Download data is not yet available.

Author Biography

Z.F DAWOOD, Mosul University

Chemistry Department
College of Education

References

- Stratton W.J. and Busch D.H., J. Amer. Chem. Soc., 82, (1960), p. 4834.

- Stratton W.J., Retting M.F. and Drury R.F., Inorg. Chem. Acta, 3, (1969), p. 97.

- Sataphathy S. and Sahoo B., J. Inorg. Nucl. Chem., 32, (1970), p.2223.

- Mital S.P., Singh R.V. and Tandon J.P., J. Inorg. Nucl. Chem., 43, (1981), p. 533.

- Daoud K.M., Dawood Z.F. and Mohammad M.M., J. Indian Chem. Soc., 71, (1994), p. 263.

- Clarkson S.G. and Basolo F., Inorg. Chem., 12, (1993), p. 1528.

- Wayland B.B., Abd-Elmageed M.F. and Mohns L.P., Inorg. Chem., 14, (1975), p. 1456.

- Kanoongo N. Singh R.V. and Tandon J.P., Synth. React. Inorg. Met.-Org. Chem., 17, (1987), p. 837.

- Reddy K.H., Reddy D.V. and Reddy K.G., Indian J. Chem., Sec. A, 27, (1988), p. 812.

- Kumar Y. and Tolani S.P., Croat Chem. Acta, 62, (1989), p. 73.

- Shukla P.R. and Jaiswal A.M., J. Indian Chem. Soc., 57, (1980), p. 29.

- Sharma C.L. and Islam M.S., J. Indian Chem. Soc., 64, (1987), p. 246.

- Nagar R. and Sharma R.C., J. Indian Chem. Soc., 65, (1988), p. 240.

- Vogel A.I., "Textbook of Quantitative Inorganic Analysis", (1981), Longmans, 4th ed., 338.

- Vogel A.I., "Textbook of Practical Organic Chemistry", (1964), Longmans Green, London, 3rd ed., 722, 344.

- Geary W.J., Coord. Chem. Rev.,7, (1971), p. 81.

- Nakamoto K., "Infra red and Raman Spectra of Inorganic and Coordination Compounds", (1978), John Wiley, New York, 3rd ed.

- Dawood Z.F., Basrah J. Science, C, 15(1), (1997), p. 79.

- Kanoongo N., Singh R. and Tandon J.P., Transition Met. Chem., 12, (1978), p. 271.

Downloads

Published

2000-12-01

How to Cite

DAWOOD, Z. (2000). NEW COMPLEXES OF INDIUM (111) CONTAINING MIXED LIGANDS (SEMICARBAZONES and BENZALDAZINES). Sciences & Technology. A, Exactes Sciences, (14), 47–50. Retrieved from https://revue.umc.edu.dz/a/article/view/1669

Issue

Section

Articles