THE EFFECT OF IRON CONTENT ON THE PHASE TRANSFORMATION OF TIO2 NANOCRISTALLINE POWDERS PREPARED BY SOL GEL PROCESS

Authors

  • S BOUDJADAR Université Constantine 1 (ex mentouri)
  • S MAHMOUDI Université Constantine 1 (ex mentouri)
  • L GUERBOUS Nuclear research center, Algiers (CRNA)

Keywords:

Titanium dioxide, Sol-gel, Iron ion doping, Anatase, rutile, phase transformation

Abstract

Pure and Fe3+ - doped TiO2 nanoparticles were prepared by sol–gel method, using TiCl4 and FeCl3 as starting materials, ethanol as a solvent and ammonium hydroxide as a catalyst. The structural, morphological and optical properties of as prepared powders were investigated by X-ray diffraction, scanning electron microscopy and UVvisible absorption spectroscopy. The quality of the samples was examined by Infra-red absorption spectroscopy and room temperature photoluminescence (PL). All samples shows anatase phase except the 0.1 mol % Fe3+ - doped TiO2 sample, which rutile phase was appeared. The particle sizes decrease when the iron content increases.
From SEM images, the morphology and size of particles were affected by amount of doped metal. The absorption edge of Fe3+ - doped TiO2 shifted towards visible spectrum when the Fe3+ - doped concentration increased. from the infra-red absorption spectra, the materials showed a highly pure and strongly surface hydrated, the materials shows main PL emission peaks appears in UV, and visible regions.

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Author Biographies

S BOUDJADAR, Université Constantine 1 (ex mentouri)

Laboratoire de Céramiques

Département de Physique

 

S MAHMOUDI, Université Constantine 1 (ex mentouri)

Laboratoire de Céramiques

Département de Physique

L GUERBOUS, Nuclear research center, Algiers (CRNA)

Department of laser

References

Chen X, Mao SS (2007) Chemical Reviews 107: 2891-2959

Andersson M, Osterlund L, Ljungstrom S, Palmavist A (2002) The Journal of Physical Chemistry B 106 (41): 10674-10679

Tada H, Hattori A, Tokihisa Y, Imai K, Tohge N, Ito S (2000) the Journal of Physical Chemistry B 104 (19): 4585–4587

Garcia-Serrano J, Gomez-Hernandez E, Ocampo- Fernandez M, Pal U (2009) Current Applied Physics 9 : 1097–1105

Wang W, Gu B, Liang L, Hamilton WA, Wesolowski DJ (2004) The Journal of Physical Chemistry B 108 (39):14789–14792

Stojanovic B D, Marinkovic Z V, Brankovic G O, Fidancevska E(2000) Journal of Thermal Analysis and Calorimetry 60: 595-604

Gouma P I, Mills MJ (2001) Journal of the American Ceramic Society 84: 619-622

Varghese OK , Gong D, Paulose M, Grimes CA, Dickey EC (2003) Journal of Materials Research 18:156-165

Fernandez-Garcia M, Wang X, Belver C, Hanson JC, Rodriguez JA (2007) The Journal of Physical Chemistry C 111 : 674-682

Izmajlowicz MAT, Flewitt A J, Milne WI, Morrison NA (2003) Journal of Applied Physics 94: 7535-7541

Epifani M, Giannini C, Tapfer L, Vasanelli L (2000) Journal of the American Ceramic Society 83: 2385-2393

Tseng IH, Wu GCS, Chou H (2004) Journal of Catalysis 221: 432-440

Kang M, Mol J (2003) Journal of Molecular Catalysis 197:173-179

Perkas N, Palchik O, Drukental I, Nowik I, Gofer Y, Koltypin Y, Gedanken A (2003) Journal of Physics Chemistry B 107: 8772-8778.

Zhu YF, Zhang L, Wang L, Fu Y, Gao LL (2001) Journal of Materials Chemistry 11: 1864–1868

Zhang L, Zhu Y, He Y, Li W, Sun H (2003) Applied Catalysis B, Environmental 40: 287-292.

Li Z, Shen W, He W, Zu X (2008) Journal of Hazardous Materials 155: 590-594

Peng F, Cai L, Yu H, Wang H, Yang J (2008) Journal of Solid State Chemistry 181: 130–136

Janes R, Knightley LJ, Harding CJ (2004) Dyes Pigments 62: 199–212

Peng F, Cai L, Huang L, Yu H, Wang H (2008) Journal of Physics and Chemistry of Solids 69: 1657–1664

Shi JW, Zheng JT, Hu Y, Zhao YC (2007) Materials Chemistry and Physics 106: 247–249

Moon J, Takagi H, Fujishiro Y, Awano M (2001) Journal of Materials Science 36: 949-955

Ronconi C M, Ribeiro C, Bulhoes LOS, Pereira EC (2008) Journal of Alloys and Compounds 466: 435-438

Li W, Ni C, Lin H, Huang CP, Shah SI (2004) Journal of Applied Physics 96: 6663-6668

Mahshid S, Askari M, Ghamsari M S, Afshar N, Lahuti S (2009) Journal of Alloys and Compounds 478 : 586-589

Peiro AM, Peral J, Domingo C, Momenech X, Ayllon JA (2001) Chemistry of Materials13: 2562-2567.

Sun A, Li Z, Li M, Xu G, Li Y, Cui P (2010) Powder Technology 210 :130-137

T. Bezrodna, G. Puchkovska, V. Shimanovska, I. Chashecnikova, T. Khalyavka, Baran J (2003) Applied Surface Science 214: 222-231

Kanna M, Wongnawa S, Material Chemistry and Physics 110 (2008) 166-175

Li GS, Li LP, Goates JB, Woodfield BF (2005) Journal of the American Chemical Society 127: 8659-8666

Wang P, Wang DJ, Li HY, Xie TF, H. Z. Wang, Z. L. Du (2007) Journal of Colloid and Interface Science 314: 337-340

Cao YA, Yang WS, Zhang WF, Liu GZ, Yue P (2004) New Journal of Chemistry 28: 218–222

Li XZ, Li FB (2001) Environnemental Science and Technology 35 : 2381–2387

Kim DH, Hong HS, Kim SJ, Song JS, Lee KS (2004) Journal of Alloys and Compounds 375: 259–264

Ghorai TK, Biswas S K, Pramanik P (2008) Applied Surface Science 254: 7498-7504

Wang XH, Li JG, Kamiyama H, Katada M, Ohashi N, Moriyoshi Y et al (2005) Journal of American Chemistry society 127: 10982-10990

Jia HM, Xu H, Hu Y, Tang YW, Zhang LZ (2007) Electrochemistry Communications 9: 354-360

Z. Zhang, Y. Yuan, Y. Fang, L. Liang, H. Ding, G. Shi, L. Jin (2007) Journal of Electrochemical society 610: 179-185

[ 39] R.S. Ningthoujam, V. Sudarsan, R.K. Vatsa, R.M. Kadam, Jagannath, A. Guptad (2009) Journal of Alloys and Compounds 486 : 864–870.

Lakshminarayana G, Yang HC, Qiu JR (2009) Journal of Alloys and Compounds 475: 569-576

Yu JG, Wang B (2010) Applied Catalysis B Environmental 94: 295-306

Serpone N, Lawless D, Khairutdinov R (1995) The journal of Physical Chemistry 99:16646-16654

Toyoda T, Hayakawa T, Abe K, Shigenari T, Shen Q (2000) Journal of Luminescence 87: 1237-1239

Huang D, Liao S, Liu J, Dang Z, Petrik L (2006) Journal of Photochemistry and Photobiology A 184: 282-288

Zhao Y, Li CZ, Liu XH , Gu F, Jiang H B, Shao W, Zhang L, He Y (2007) Materials Letters 61: 79-83

Xu J, Li L, Yan Y, Wang H, Wang X, Fu X, Li G (2008) Journal of Colloid and Interface Science 318 : 29-34

Published

2010-12-01

How to Cite

BOUDJADAR, S., MAHMOUDI, S., & GUERBOUS, L. (2010). THE EFFECT OF IRON CONTENT ON THE PHASE TRANSFORMATION OF TIO2 NANOCRISTALLINE POWDERS PREPARED BY SOL GEL PROCESS. Sciences & Technology. A, Exactes Sciences, (32), 43–48. Retrieved from https://revue.umc.edu.dz/a/article/view/19

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