PREPARATION AND CHARACTERIZATION OF SOME NITROFURANTOIN METAL COMPLEXES
الكلمات المفتاحية:
Nitrofurantoin، ligand، Titanium، Chromium، Iron.الملخص
The synthesis and characterization of two types of complexes for
nitrofurantoin of the formula [M(NFD)Cl2]Cl and [M2(NFD)2Cl2]Cl4
(Where M=Ti(III), Cr (III) and Fe(III), NFD = nitrofurantoin) were
described.
They had been characterized by their elemental analysis, molar
conductances, infrared and electronic spectra. The ligand exhibited
tetradentate manner, in both types, to form with two chloride ions the most
probable octahedral geometry around the trivalent ions.
التنزيلات
المراجع
- Delgado J.N., Remer W.A., Textbook of Organic Medicinal and Pharmaceutical Chemistry, 9th Ed. (1991). J. Lippincott Co. p.157.
- Zuman P., Microchem. J., 57, (1997), p.4.
- Morales A., Toral M. and Richter P., Analysit, 109, (1984), p. 633.
- Sulaiman S.T. and Hazim F., National J. of Chem., 5, (2002), p.61.
- Sher A., Weber W., Gomiscek M. and Gomiscek S., International J. Pharm., 90, (1993), p.1818.
- Bravo A. and Anawna J.R., J. Coord. Chem., 44 (1-2), (1998), p.173.
- Khallow K.I., Iraqi J. Chem., 27(4), (2001), p.925.
- Pellerito L., Maggio F., Consiglio M., Pellerito A., Stocco G.C. and Grimaudo S., Applied Oranometallic Chem., 9(8), (1995),
p.227.
- Amin A.S., Spect. Lett., 29(6), (1996), p. 1003.
- Navarro P.G., El-Bekkouri A. and Reinoso E.R., Analyst, 123(11), (1998), p.2263.
- Krimpen P.C., Van Bennkom W.P. and Bull A., Pharm. Weekbl-Sci., 10(9), (1988), p.259.
- Abdel-Gawad F.M., El-Guindi N.M. and Ibrahim M.M., J. Drug Research, 17(1-2), (1987), p. 197.
- Khallow K.I., Iraqi J. Chem., 27(1), (2001), p.159.
- Vogel A.L., Textbook of Quantitative Inorganic Analysis, 4th Ed., (1981), p.491.
- Geary W.J., Coord. Chem. Rev., 7, (1971), p.81.
- Silverstein R. M. and Webster F.X., Spectrometric Identification of Organic Compounds, 6th. Ed., John Wiley & Sons Inc., (1997),
p.106.
- Kanoongo N., Sing R.V. and Tondon J.P., Synth. React. Inorg. Met-Org. Chem., (17, (1989), p. 837.
- Al-Alaf T.A.K. and Taqa A.A., Synth., React. Inorg. Met-Org. Chem., 27, (1997), p. 985.
- Dawood Z.F., Science and Technologie, 17, (2002), p.35.
- Topping G., Spectrochimica Acta, 21, (1965), p.17, 43.
- Jassim A.H., Al-Hasani and Al-Mumin T.M., National J. Chem., 2, (2001), p.215.
- Lever A.B.P., J. Chem. Educ., 45(11), (1968), p.711.
- Figgis B.N., Introduction to Ligand Fields, Interscience Publishers, (1966).
